I have been perfecting my own
method of steel making over the last few years. I use a solid state direct
method of reducing iron oxide to metallic iron in a bloomery style furnace.
Carbon dissolves into the iron to make steel in a relatively controlled process.
The furnace is made of bricks
made of sand, cement and vermiculite. The top of the stack is made of refractory
blanket coated with furnace cement.
The air is provided by a
shop-vac and the tuyeres are made of simple iron pipe plumbing fittings.
I have tried different types
of ore based on availability: from hematite (Fe2O3)
to magnetite (Fe3O4)
and taconite. I found hematite to give the best results for me but any of these
ores can be effectively reduced to metallic iron in the right conditions.
At around 600ºF~1500ºF Fe3O4
+ CO → 3FeO + CO2
At around 800ºF~1800ºF FeO + CO → Fe + CO2
At above 1400ºF~1600ºF 3Fe + C → Fe3C
Charcoal is the fuel and the
source of carbon. Mixed with oxygen at the right temperature will form carbon
monoxide which is the reducing agent. Depending on the height of the stack, the
duration of time during which the ore is exposed to the reducing atmosphere and
the temperature there will be a reduction of the iron oxide to metallic iron and
absorption of carbon. The two processes needed to make steel. The usual result
of this type of furnace is a mixture of cast iron at the bottom, high carbon
steel above and some wrought iron on top of a non-homogeneous globular mass
called "the bloom."
The quality of the slag and
the atmosphere in the hearth of the furnace will be greatly responsible for the
final carbon content in the bloom.