In my opinion there are three stages of wine
aging.
The first stage is oak or barrel aging where the
water, alcohol and acid present in wine extract chemicals, sugars and flavors
from the wood. This stage is anywhere from one week to 2 years long
and the rate of extraction drops off hyperbolically with time.
The amount of flavors extracted in the first use of a barrel will never
be reached again. The amount of time required for a certain level
of extraction for the third use of a barrel is twice the time required
for the second use. Wineries age part of a batch of wine in new barrels
and the rest in old barrels to achieve the desired level of oak while minimizing
cost and time. In addition to extracting flavors, sugars and tannin
from the oak, the wine is concentrated during barrel aging because water
and alcohol evaporate through the porous wood. Five percent, on average,
of the wine evaporates per year of barrel aging so there is less wine available
for sale. Humidity and air circulation around the barrels affects
the evaporation rates of water and alcohol. If humidity is low, water
evaporates faster than alcohol and the ethanol content of the wine increases.
If the humidity is high, then alcohol evaporates faster than water and
the ethanol content drops. The humidity required for constant alcohol
content is about 68% relative humidity. A very good, but highly technical
discussion of barrel aging of wine is "Maturation
of Wines and Spirits: Comparisons, Facts, and Hypotheses" Vernon L.
Singleton, Am. J. of Enol. Vitic., Vol 46, No. 1, 1995.
Dr. Singleton, who is now retired, dedicated his career at UC Davis to
the study of how wine ages.
The second stage of aging is bottle aging where
slow chemical reactions combine chemicals in the wine to produce new flavors
that were not present when the wine was bottled. Other chemicals
combine and are too heavy to remain is suspension, so they settle to the
bottom of the bottle as sediment. Wines that are meant to be aged
a long time have a high level of tannin when they are bottled from time
in contact with the grapes skins and oak. These tannins help preserve
the wine, but over time attach themselves to chemicals in the wine and
settle out. Because of this, tannin is known as a finning agent.
Wines with high levels of tannin taste bitter (like chewing on a used tea
bag) when they are young and become smoother or more mellow as the tannin
level drops. Some of the sharper/harsher flavors present in young
wines are removed by the tannin and settle out as well.
The third stage of aging occurs once you open
the bottle and expose the wine to air. Some wines benefit from this
more than others and some people decant wines into wide mouth carafes to
"allow the wine to breathe." The breathing process allows strong
odors to bleed off and oxidizes the wine by bring it into contact with
the oxygen present in air. Too much breathing time or leaving wine
in a half empty bottle for several days can ruin the wine through too much
oxidation.